Structural, Magnetic, and Electrochemical Characterization of Iron(III) and Cobalt Complexes with Penta?N 3 O 2 ?dentate Ligands
نویسندگان
چکیده
Six new mononuclear [FeIII(LBr,Cl)X]-complexes (LBr,Cl is the dianionic penta-N3O2-dentate Schiff base ligand N,N?-bis(2’-hydroxy-3-bromo-5-chlorobenzylidene)-1,6-diamino-3-azahexane; X: Cl?, N3?, NCO?, NCS?, NCSe?, CN?) were synthesized and their structures, magnetic electrochemical properties studied. Structure analysis measurements showed that [FeIII(LBr,Cl)CN] in low spin state other five complexes are high states. Furthermore, trinuclear mixed valent cobalt complex {[CoIII(LH,H)CN]2[CoII(1-methylimidazole)3(H2O)]} was prepared its behavior
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ژورنال
عنوان ژورنال: European Journal of Inorganic Chemistry
سال: 2021
ISSN: ['1434-1948', '1099-0682']
DOI: https://doi.org/10.1002/ejic.202100081